Issue 15, 2007
From the journal:

Chemical Communications

A bimetallic N-heterocyclic carbene complex featuring a short Cr–Cr distance†

Kevin A. Kreisel,a   Glenn P. A. Yapa  and  Klaus H. Theopold*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Center for Catalytic Science and Technology, University of Delaware, Newark, USA
E-mail: theopold@udel.edu
Fax: +1 (302)831-4269
Tel: +1 (302)831-1546

Abstract

The alkylation of a chelating bis(carbene) complex of CrCl2 yields an unusual bimetallic complex featuring a short Cr–Cr distance, novel ligand coordination, and CH3 ligand exchange.

Graphical abstract: A bimetallic N-heterocyclic carbene complex featuring a short Cr–Cr distance

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Article information

DOI
https://doi.org/10.1039/B616685G
Article type
Communication
Submitted
14 Nov 2006
Accepted
26 Jan 2007
First published
16 Feb 2007

Chem. Commun., 2007, 1510-1511

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A bimetallic N-heterocyclic carbene complex featuring a short Cr–Cr distance

K. A. Kreisel, G. P. A. Yap and K. H. Theopold, Chem. Commun., 2007, 1510 DOI: 10.1039/B616685G

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