Issue 14, 2007
From the journal:

Chemical Communications

57Fe Mössbauer spectroscopy predicts superstructure for K0.08[CuII(N,N′app)Cl]2[FeIII(CN)6]·0.92H3O·3H2O

Uday Mukhopadhyay,a   C. Matthias Grunert,b   Joachim Kusz,c   Sergey Reiman,b   P. Gütlich*b  and  Ivan Bernal*a  

* Corresponding authors

a University of Houston, Chemistry Department, Houston, TX 77204-5003, USA
E-mail: ibernal@uh.edu

b Johannes Gutenberg Universität Mainz, Institut für Anorganische Chemie und Analytische Chemie, Staudingerweg 9, D-55099 Mainz, Germany
E-mail: guetlich@uni-mainz.de

c University of Silesia, Institute of Physics, ul. Uniwersytecka 4, PL-40007 Katowice, Poland

Abstract

The compound [Cu(N,N′app)Cl]2[Fe(CN)6]·xH2O, with N,N′app being bis(N,N′-3-aminopropylpiperazine), was prepared and its structure determined by single crystal X-ray analysis, confirming a ratio of two copper complexes to one iron complex; 57Fe Mössbauer spectra showed three quadrupole doublets typical of iron(III) low spin species which call for the presence of a superstructure.

Graphical abstract: 57Fe Mössbauer spectroscopy predicts superstructure for K0.08[CuII(N,N′app)Cl]2[FeIII(CN)6]·0.92H3O·3H2O

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Article information

DOI
https://doi.org/10.1039/B615130B
Article type
Communication
Submitted
18 Oct 2006
Accepted
14 Feb 2007
First published
07 Mar 2007

Chem. Commun., 2007, 1444-1446

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57Fe Mössbauer spectroscopy predicts superstructure for K0.08[CuII(N,N′app)Cl]2[FeIII(CN)6]·0.92H3O·3H2O

U. Mukhopadhyay, C. M. Grunert, J. Kusz, S. Reiman, P. Gütlich and I. Bernal, Chem. Commun., 2007, 1444 DOI: 10.1039/B615130B

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