Highly selective R,S-coordination of non racemic (1R,2R)-(1,2-dialkyl)-1,2-diamine cyclohexane derivatives to palladium dichloride

Esfandiar Rafii; Benjamin Dassonneville; Andreas Heumann

doi:10.1039/B613961B

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Highly selective R,S-coordination of non racemic (1R,2R)-(1,2-dialkyl)-1,2-diamine cyclohexane derivatives to palladium dichloride†

Esfandiar Rafii,^a Benjamin Dassonneville^a and Andreas Heumann*^a

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* Corresponding authors

^a Université Paul Cézanne, UMR CNRS 6180 ‘Chirotechnologies: Catalyse et Biocatalyse’, Faculté Saint-Jérôme, Case A 62, 13397 Marseille Cedex 20, France
E-mail: andreas.heumann@univ-cezanne.fr
Fax: 33 49128 8278
Tel: 33 49128 8278

Abstract

In non-racemic (1R,2R)-(1,2-dialkyl)-1,2-diaminocyclohexane palladium dichloride complexes the C₂ symmetry of the diamine ligand is broken, resulting in selective R,S-coordination.

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Article information

DOI: https://doi.org/10.1039/B613961B
Article type: Communication
Submitted: 26 Sep 2006
Accepted: 15 Dec 2006
First published: 12 Jan 2007

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Chem. Commun., 2007, 583-585

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Highly selective R,S-coordination of non racemic (1R,2R)-(1,2-dialkyl)-1,2-diamine cyclohexane derivatives to palladium dichloride

E. Rafii, B. Dassonneville and A. Heumann, Chem. Commun., 2007, 583 DOI: 10.1039/B613961B

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Chemical Communications

Highly selective R,S-coordination of non racemic (1R,2R)-(1,2-dialkyl)-1,2-diamine cyclohexane derivatives to palladium dichloride†

Abstract

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Highly selective R,S-coordination of non racemic (1R,2R)-(1,2-dialkyl)-1,2-diamine cyclohexane derivatives to palladium dichloride

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