Issue 6, 2007
From the journal:

Chemical Communications

Experimental and theoretical evidence of the first Au(i)⋯Bi(iii) interaction†‡

Eduardo J. Fernández,*a   Antonio Laguna,*b   José M. López-de-Luzuriaga,a   Miguel Monge,a   Mihai Nema,ac   M. Elena Olmos,a   Javier Péreza  and  Cristian Silvestruc  

* Corresponding authors

a Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La Rioja, UA-CSIC. Complejo Científico-Tecnológico, Logroño, Spain
E-mail: eduardo.fernandez@dq.unirioja.es
Fax: +34 941 299 621
Tel: +34 941 299642

b Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, Zaragoza, Spain
E-mail: alaguna@unizar.es
Fax: +34 976 761187
Tel: +34 976 761185

c Facultatea de Chimie si Inginerie Chimica, Universitatea Babes-Bolyai, Cluj-Napoca, Romania

Abstract

Complex [Au(C6F5)2][Bi(C6H4CH2NMe2-2)2] 1 displays the first example of an interaction between Au(I) and Bi(III), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%).

Graphical abstract: Experimental and theoretical evidence of the first Au(i)⋯Bi(iii) interaction

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Article information

DOI
https://doi.org/10.1039/B613365G
Article type
Communication
Submitted
15 Sep 2006
Accepted
25 Oct 2006
First published
15 Nov 2006

Chem. Commun., 2007, 571-573

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Experimental and theoretical evidence of the first Au(I)⋯Bi(III) interaction

E. J. Fernández, A. Laguna, J. M. López-de-Luzuriaga, M. Monge, M. Nema, M. E. Olmos, J. Pérez and C. Silvestru, Chem. Commun., 2007, 571 DOI: 10.1039/B613365G

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