Issue 3, 2007
From the journal:

Chemical Communications

First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH[double bond, length as m-dash]CH-py)2·2CH3CN, M = CoII, MnII†

Konstantin S. Gavrilenko,‡a   Yann Le Gal,a   Olivier Cador,a   Stéphane Golhena  and  Lahcène Ouahab*a  

* Corresponding authors

a Organométalliques et Matériaux Moléculaires, UMR 6226 CNRS-UR1 Sciences Chimiques de Rennes, Université de Rennes 1, Rennes Cedex, France
E-mail: lahcene.ouahab@univ-rennes1.fr
Fax: +33 2 23 23 68 40
Tel: +33 2 23 23 56 59

Abstract

The first paramagnetic homo- and hetero-metallic trinuclear complexes with redox active ligands derived from TTF are synthesized, the central metal ion has an octahedral coordination sphere while the outer CoII ions are in a distorted bipyramidal surrounding, bearing TTF-ligands, the magnetic properties show antiferromagnetic coupling leading to a magnetic ground state.

Graphical abstract: First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH [[double bond, length as m-dash]] CH-py)2·2CH3CN, M = CoII, MnII

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Article information

DOI
https://doi.org/10.1039/B613191C
Article type
Communication
Submitted
12 Sep 2006
Accepted
11 Oct 2006
First published
26 Oct 2006

Chem. Commun., 2007, 280-282

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First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH[double bond, length as m-dash]CH-py)2·2CH3CN, M = CoII, MnII

K. S. Gavrilenko, Y. L. Gal, O. Cador, S. Golhen and L. Ouahab, Chem. Commun., 2007, 280 DOI: 10.1039/B613191C

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