Issue 3, 2007

π-Bonding encapsulation in aryl-substituted lanthanide selenolates: monomeric compounds with apparent low-coordinate metal atoms

Abstract

Reaction of LnCl3 with KSeAr* in thf afforded the unsolvated, alkane-soluble complexes LnCl(SeAr*)2 (Ln = Nd, Pr; Ar* = 2,6-Trip2C6H3; Trip = 2,4,6-iPr3C6H2) in which the rare-earth metal cations show additional η6-π-coordination by two flanking arene rings.

Graphical abstract: π-Bonding encapsulation in aryl-substituted lanthanide selenolates: monomeric compounds with apparent low-coordinate metal atoms

Supplementary files

Article information

Article type
Communication
Submitted
25 Aug 2006
Accepted
10 Oct 2006
First published
26 Oct 2006

Chem. Commun., 2007, 275-277

π-Bonding encapsulation in aryl-substituted lanthanide selenolates: monomeric compounds with apparent low-coordinate metal atoms

S. Hauber and M. Niemeyer, Chem. Commun., 2007, 275 DOI: 10.1039/B612182A

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