Synthesis and characterization of difluoromethylene-homo[60]fullerene, C60(CF2)

Anna S. Pimenova; Andrey A. Kozlov; Alexey A. Goryunkov; Vitaliy Yu. Markov; Pavel A. Khavrel; Stanislav M. Avdoshenko; Ilya N. Ioffe; Sergey G. Sakharov; Sergey I. Troyanov; Lev N. Sidorov

doi:10.1039/B611623J

Synthesis and characterization of difluoromethylene-homo[60]fullerene, C₆₀(CF₂)

Anna S. Pimenova,^a Andrey A. Kozlov,^a Alexey A. Goryunkov,^a Vitaliy Yu. Markov,^a Pavel A. Khavrel,^a Stanislav M. Avdoshenko,^a Ilya N. Ioffe,^a Sergey G. Sakharov,^bc Sergey I. Troyanov^a and Lev N. Sidorov*^a

Author affiliations

* Corresponding authors

^a Chemistry Department, Moscow State University, Moscow 119992, Russia
E-mail: sidorov@thermo.chem.msu.ru
Fax: +7 (495) 939 12 40
Tel: +7 (495) 939 53 73

^b Kurnakov Institute of General & Inorganic Chemistry, RAS, Moscow 119991, Russia
Fax: +7(495)9521279
Tel: +7(495)9554840

^c Institute for Physical Chemistry and Problems of Ceramics, RAS, Moscow 119361, Russia
Fax: +7(495)4379893
Tel: +7(495)7181655

Abstract

Refluxing of the o-DCB solution of C₆₀ with CF₂ClCOONa and 18-crown-6 leads to formation of C₆₀(CF₂)_n (n = 1–3); the monoadduct C₆₀(CF₂) has been found to consist of the main [6,6]- and minor [5,6]-isomers, both having an open structure.

Chemical Communications

Synthesis and characterization of difluoromethylene-homo[60]fullerene, C₆₀(CF₂)

Abstract

Article information

Download Citation

Permissions

Synthesis and characterization of difluoromethylene-homo[60]fullerene, C₆₀(CF₂)

Social activity

Search articles by author

Spotlight

Advertisements