Issue 2, 2007
From the journal:

Chemical Communications

Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster†

Daniele Belletti,a   Pierre Braunstein,b   Abdelatif Messaoudi,b   Roberto Pattacini,*ab   Giovanni Predieria  and  Antonio Tiripicchioa  

* Corresponding authors

a Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Parco Area delle Scienze 17/A, Italy
E-mail: rpattacini@virgilio.it
Fax: +39 0521 905557
Tel: +39 0521 905418

b Laboratoire de Chimie de Coordination, UMR 7177 CNRS, Universitè Louis Pasteur, 4 rue Blaise Pascal, France
E-mail: braunst@chimie.u-strasbg.fr

Abstract

In the clusters [Ru3(μ3-NPPh3)(μ3-OSiMe3)(μ-X)(μC,O-OC[double bond, length as m-dash]NPPh3)(μ-CO)(CO)6] (X = NCO, 2; X = Cl, 3), which were prepared by a pyrolytic reaction of Ph3PNSiMe3 with Ru3(CO)12, the ligands result from a cluster-mediated pseudo-Hofmann rearrangement involving the μ-NCO, μ(C,O)-Ph3P[double bond, length as m-dash]N–CO and μ3-NPPh3 fragments.

Graphical abstract: Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster

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Article information

DOI
https://doi.org/10.1039/B611338A
Article type
Communication
Submitted
07 Aug 2006
Accepted
25 Sep 2006
First published
17 Oct 2006

Chem. Commun., 2007, 141-143

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Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster

D. Belletti, P. Braunstein, A. Messaoudi, R. Pattacini, G. Predieri and A. Tiripicchio, Chem. Commun., 2007, 141 DOI: 10.1039/B611338A

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