Issue 5, 2007
From the journal:

Chemical Communications

Asymmetric total synthesis of martinelline and martinellic acid†

Shuhei Ikeda,a   Masatoshi Shibuyaa  and  Yoshiharu Iwabuchi*a  

* Corresponding authors

a Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aobayama, Sendai, Japan
E-mail: iwabuchi@mail.pharm.tohoku.ac.jp
Fax: +81 22-795-6846

Abstract

Herein, we describe the first asymmetric total synthesis of (–)-martinelline ((–)-2) and the second total synthesis of (–)-martinellic acid ((–)-1) by employing a tandem Mukaiyama–Mannich reaction/aminal cyclization as the key step.

Graphical abstract: Asymmetric total synthesis of martinelline and martinellic acid

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Article information

DOI
https://doi.org/10.1039/B611121A
Article type
Communication
Submitted
01 Aug 2006
Accepted
18 Oct 2006
First published
01 Nov 2006

Chem. Commun., 2007, 504-506

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Asymmetric total synthesis of martinelline and martinellic acid

S. Ikeda, M. Shibuya and Y. Iwabuchi, Chem. Commun., 2007, 504 DOI: 10.1039/B611121A

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