Issue 2, 2007
From the journal:

Chemical Communications

Stereoselective stilbene epoxidation over supported gold-based catalysts†

Pascal Lignier,a   Franck Morfin,a   Stéphane Mangematin,a   Laurence Massin,a   Jean-Luc Rousseta  and  Valérie Caps*a  

* Corresponding authors

a Institut de Recherches sur la Catalyse (CNRS), 2 avenue Albert Einstein, 69626 Villeurbanne Cedex, France
E-mail: caps@catalyse.cnrs.fr

Abstract

The gold reference catalyst Au/TiO2 exhibits high activity in the stereoselective epoxidation of trans-stilbene in methylcyclohexane in the presence of 5 mol% TBHP, by taking part in a chain reaction involving the activation of molecular oxygen by a radical produced from methylcyclohexane.

Graphical abstract: Stereoselective stilbene epoxidation over supported gold-based catalysts

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Article information

DOI
https://doi.org/10.1039/B610546G
Article type
Communication
Submitted
24 Jul 2006
Accepted
29 Sep 2006
First published
24 Oct 2006

Chem. Commun., 2007, 186-188

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Stereoselective stilbene epoxidation over supported gold-based catalysts

P. Lignier, F. Morfin, S. Mangematin, L. Massin, J. Rousset and V. Caps, Chem. Commun., 2007, 186 DOI: 10.1039/B610546G

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