Issue 13, 2006
From the journal:

Organic & Biomolecular Chemistry

FluoRuGel: a versatile catalyst for aerobic alcohol oxidation in supercritical carbon dioxide

Rosaria Ciriminna,a   Sandro Campestrinib  and  Mario Pagliaro*a  

* Corresponding authors

a Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via La Malfa 153, Palermo, Italy
E-mail: mario.pagliaro@gmail.com

b Dipartimento di Scienze Chimiche, Università degli Studi, via Marzolo 1, Padova, Italy

Abstract

FluoRuGel—a hybrid fluorinated silica glass doped with TPAP (tetra-n-propylammonium perruthenate)—is a versatile catalyst for the aerobic oxidation of different alcohols in dense phase CO2 with marked stabilization and activity enhancement of perruthenate upon its confinement in the sol–gel fluorinated silica matrix. A brief competitive analysis shows large potential rewards.

Graphical abstract: FluoRuGel: a versatile catalyst for aerobic alcohol oxidation in supercritical carbon dioxide

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Article information

DOI
https://doi.org/10.1039/B604663K
Article type
Paper
Submitted
30 Mar 2006
Accepted
22 May 2006
First published
07 Jun 2006

Org. Biomol. Chem., 2006,4, 2637-2641

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FluoRuGel: a versatile catalyst for aerobic alcohol oxidation in supercritical carbon dioxide

R. Ciriminna, S. Campestrini and M. Pagliaro, Org. Biomol. Chem., 2006, 4, 2637 DOI: 10.1039/B604663K

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