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Issue 14, 2006
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Stereochemical relays: communication via conformation

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Abstract

Stereochemistry is information, and stereoselective reactions are the means by which that information may be communicated within and between molecules. The control of remote stereogenic centres can be achieved by stereochemical relay, and the use of thermodynamic control over conformational preference is turning out to be a very powerful method for long-range transmission of stereochemical information.

Graphical abstract: Stereochemical relays: communication via conformation

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Publication details

The article was received on 29 Mar 2006, accepted on 25 May 2006 and first published on 15 Jun 2006


Article type: Emerging Area
DOI: 10.1039/B604548K
Citation: Org. Biomol. Chem., 2006,4, 2667-2678
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    Stereochemical relays: communication via conformation

    J. Clayden and N. Vassiliou, Org. Biomol. Chem., 2006, 4, 2667
    DOI: 10.1039/B604548K

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