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Issue 7, 2006
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Asymmetric allylation of aryl aldehydes: studies on the scope and mechanism of the palladium catalysed diethylzinc mediated umpolung using phosphoramidite ligands

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Abstract

Using modular, monodentate phosphoramidite ligands, enantioselective palladium catalysed diethylzinc mediated allylation of aldehydes was achieved. The scope of the asymmetric C–C bond formation was investigated with respect to nucleophilic and electrophilic components and an alternative reaction mechanism is proposed based on our findings.

Graphical abstract: Asymmetric allylation of aryl aldehydes: studies on the scope and mechanism of the palladium catalysed diethylzinc mediated umpolung using phosphoramidite ligands

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Supplementary files

Article information


Submitted
21 Dec 2005
Accepted
01 Feb 2006
First published
17 Feb 2006

Org. Biomol. Chem., 2006,4, 1278-1283
Article type
Paper

Asymmetric allylation of aryl aldehydes: studies on the scope and mechanism of the palladium catalysed diethylzinc mediated umpolung using phosphoramidite ligands

G. P. Howell, A. J. Minnaard and B. L. Feringa, Org. Biomol. Chem., 2006, 4, 1278
DOI: 10.1039/B518165H

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