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Issue 4, 2006
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PegPhos: a monodentate phosphoramiditeligand for enantioselective rhodium-catalysed hydrogenation in water

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Abstract

A BICOL derived monodentate phosphoramidite ligand gives ee's up to 89% in the enantioselective Rh-catalysed hydrogenation of N-acyl dehydroalanine using water as the solvent.

Graphical abstract: PegPhos: a monodentate phosphoramidite ligand for enantioselective rhodium-catalysed hydrogenation in water

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Article information


Submitted
01 Dec 2005
Accepted
03 Jan 2006
First published
13 Jan 2006

Org. Biomol. Chem., 2006,4, 613-615
Article type
Communication

PegPhos: a monodentate phosphoramidite ligand for enantioselective rhodium-catalysed hydrogenation in water

R. Hoen, S. Leleu, P. N. M. Botman, V. A. M. Appelman, B. L. Feringa, H. Hiemstra, A. J. Minnaard and J. H. van Maarseveen, Org. Biomol. Chem., 2006, 4, 613
DOI: 10.1039/B517096F

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