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Issue 4, 2006
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PegPhos: a monodentate phosphoramidite ligand for enantioselective rhodium-catalysed hydrogenation in water

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Abstract

A BICOL derived monodentate phosphoramidite ligand gives ee's up to 89% in the enantioselective Rh-catalysed hydrogenation of N-acyl dehydroalanine using water as the solvent.

Graphical abstract: PegPhos: a monodentate phosphoramidite ligand for enantioselective rhodium-catalysed hydrogenation in water

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Publication details

The article was received on 01 Dec 2005, accepted on 03 Jan 2006 and first published on 13 Jan 2006


Article type: Communication
DOI: 10.1039/B517096F
Citation: Org. Biomol. Chem., 2006,4, 613-615

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    PegPhos: a monodentate phosphoramidite ligand for enantioselective rhodium-catalysed hydrogenation in water

    R. Hoen, S. Leleu, P. N. M. Botman, V. A. M. Appelman, B. L. Feringa, H. Hiemstra, A. J. Minnaard and J. H. van Maarseveen, Org. Biomol. Chem., 2006, 4, 613
    DOI: 10.1039/B517096F

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