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Issue 11, 2006
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15-Membered triolefinic macrocycles as stabilizers of palladium(0) nanoparticles

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Abstract

15-Membered triolefinic macrocycles form complexes with palladium(0). However, metal nanoparticles are formed instead of discrete complexes if substituents provided with the ability to stabilize nanoparticles are incorporated into the structure of the macrocycle. Ancillary substituents include fluorous and polyoxyethylenated chains. The role of initial organometallic coordination in the early steps of nanoparticle formation is underlined.

Graphical abstract: 15-Membered triolefinic macrocycles as stabilizers of palladium(0) nanoparticles

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Article information


Submitted
19 Jun 2006
Accepted
24 Jul 2006
First published
31 Aug 2006

New J. Chem., 2006,30, 1584-1594
Article type
Paper

15-Membered triolefinic macrocycles as stabilizers of palladium(0) nanoparticles

A. Serra-Muns, R. Soler, E. Badetti, P. de Mendoza, M. Moreno-Mañas, R. Pleixats, R. M. Sebastián and A. Vallribera, New J. Chem., 2006, 30, 1584
DOI: 10.1039/B608673J

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