Two complex solid state structures of para-sulfonato-calix[8]arene are described, showing extremes in the macrocyclic conformation; one is planar and nearly circular, the other an inverted double cone. The differences in the molecular conformations lead to highly different packing arrangements in the structures.
![Graphical abstract: Conformational extremes in the supramolecular assemblies of para-sulfonato-calix[8]arene](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=B604349F&imageInfo.ImageIdentifier.Year=2006)
F. Perret, V. Bonnard, O. Danylyuk, K. Suwinska and A. W. Coleman, New J. Chem., 2006, 30, 987 DOI: 10.1039/B604349F
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