Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)

Inma Angurell; João C. Lima; Lara-Isabel Rodríguez; Laura Rodríguez; Oriol Rossell; Miquel Seco

doi:10.1039/B518356A

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Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)†

Inma Angurell,^a João C. Lima,^b Lara-Isabel Rodríguez,^a Laura Rodríguez,^a Oriol Rossell*^a and Miquel Seco^a

Author affiliations

* Corresponding authors

^a Departament de Química Inorgànica, Universitat de Barcelona, Martí i Franquès, 1-11, E-08028 Barcelona, Spain
E-mail: oriol.rossell@qi.ub.es

^b Departamento de Química, Centro de Química Fina e Biotecnologia-REQUIMTE, Universidade Nova de Lisboa, 2829-516 Monte de Caparica, Portugal

Abstract

The reaction of [Re(bipy)(CO)₃(C [triple bond, length as m-dash] Cpy)] with two carbosilane dendrimers containing terminal (p-cymene)Ru(triflate)₂ units gives bimetallic dendrimers functionalised with (p-cymene)Ru(triflate)(pyCC)Re(bipy)(CO)₃ units. Dendrimers of this kind can be envisaged as formed by two metal layers: the internal, constituted by ruthenium atoms, and the external, by rhenium metals. The luminescent properties of these species are only attributed to the rhenium moieties.

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Article information

DOI: https://doi.org/10.1039/B518356A
Article type: Paper
Submitted: 03 Jan 2006
Accepted: 25 Apr 2006
First published: 06 Jun 2006

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New J. Chem., 2006,30, 1004-1008

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Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)

I. Angurell, J. C. Lima, L. Rodríguez, L. Rodríguez, O. Rossell and M. Seco, New J. Chem., 2006, 30, 1004 DOI: 10.1039/B518356A

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New Journal of Chemistry

Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)†

Abstract

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Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)

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