Synthesis and molecular structures of the first phosphoranylidene complexes of rare earth metals

Konstantin A. Rufanov; Bernd H. Müller; Anke Spannenberg; Uwe Rosenthal

doi:10.1039/B514439F

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Synthesis and molecular structures of the first phosphoranylidene complexes of rare earth metals†‡

Konstantin A. Rufanov,*^a Bernd H. Müller,^a Anke Spannenberg*^a and Uwe Rosenthal^a

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^a Leibniz-Institut für Organische Katalyse an der Universität Rostock, Albert-Einstein-Straße 29A, Rostock, Germany
E-mail: k_rufanov@gmx.de
Fax: +49 (0)381 1281 5000

Abstract

Metallation of the donor-functionalised ylide ligand Ph₃P [double bond, length as m-dash] CH–(o-CH₃OC₆H₄) with homoleptic alkyl and aryl complexes of yttrium and lutetium furnished unprecedented phosphoranylidene complexes, featuring a central μ₂-M₂C₂ core.

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DOI: https://doi.org/10.1039/B514439F
Article type: Letter
Submitted: 11 Oct 2005
Accepted: 24 Nov 2005
First published: 09 Dec 2005

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New J. Chem., 2006,30, 29-31

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Synthesis and molecular structures of the first phosphoranylidene complexes of rare earth metals

K. A. Rufanov, B. H. Müller, A. Spannenberg and U. Rosenthal, New J. Chem., 2006, 30, 29 DOI: 10.1039/B514439F

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New Journal of Chemistry

Synthesis and molecular structures of the first phosphoranylidene complexes of rare earth metals†‡

Abstract

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Synthesis and molecular structures of the first phosphoranylidene complexes of rare earth metals

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