Issue 32, 2006
From the journal:

Journal of Materials Chemistry

Self-assembly of cubic phenylene bridged mesoporous hybrids from allylorganosilane precursors

Mahendra P. Kapoor,*a   Masaaki Yanagi,a   Yuuki Kasama,a   Takuji Yokoyama,a   Shinji Inagaki,b   Toyoshi Shimada,c   Hironobu Nanbua  and  Lekh R. Junejaa  

* Corresponding authors

a Taiyo Kagaku Co. Ltd., Nano-Function Division, 1-3-1 Takaramachi, Yokkaichi, Japan
E-mail: mkapoor@taiyokagaku.co.jp
Fax: +81 59 347 5417
Tel: +81 59 347 5410

b Toyota Central R&D Laboratories Inc., Nagakute, Aichi, Japan

c Nara National College of Technology, 22 Yata-cho, Yamatokoriyama, Nara, Japan

Abstract

The synthesis of three-dimensional (Pm3n) cubic phenylene-bridged hybrid mesoporous silica material using a novel allylorganosilane precursor 1,4-bis(triallylsilyl)phenylene and cetyltrimethylammoniumchloride (C16TMACl) as a structure-directing agent in acidic medium is presented. Sulfonic acid functionalized derivatives of these materials are effective in Friedel–Crafts acylation reactions and in controlling the atmosphere emission of volatile organic compounds, which are responsible for ground level ozone, air toxicity and smog.

Graphical abstract: Self-assembly of cubic phenylene bridged mesoporous hybrids from allylorganosilane precursors

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Article information

DOI
https://doi.org/10.1039/B607133C
Article type
Paper
Submitted
19 May 2006
Accepted
20 Jun 2006
First published
06 Jul 2006

J. Mater. Chem., 2006,16, 3305-3311

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Self-assembly of cubic phenylene bridged mesoporous hybrids from allylorganosilane precursors

M. P. Kapoor, M. Yanagi, Y. Kasama, T. Yokoyama, S. Inagaki, T. Shimada, H. Nanbu and L. R. Juneja, J. Mater. Chem., 2006, 16, 3305 DOI: 10.1039/B607133C

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