Organic hydroperoxides undergo smooth nucleophilic displacement reactions with alkyl bromides in the presence of 30% water solution of NaOH in several ionic liquids (ILs) at room temperature to afford the corresponding dialkyl peroxides in excellent yields under extremely mild conditions. Additionally, symmetrical dialkyl peroxides were obtained in ionic liquids as solvent with good yields.
S. Baj, A. Chrobok and S. Derfla, Green Chem., 2006, 8, 292 DOI: 10.1039/B513863A
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