Issue 1, 2006

Gold nanoparticle-catalysed [3 + 2]dipolar cycloaddition of 1,6-allenynebenzaldehydes: construction of polycyclic ring systems

Abstract

We have isolated spherical-shaped monodispersed 12–14 nm range gold nanoparticles, when o-1,6-allenylbenzaldehyde underwent a novel mode of tandem cycloaddition and cyclization using AuCl3 precatalyst. This cyclization can be found in the construction of many polycyclic natural product skeletons.

Graphical abstract: Gold nanoparticle-catalysed [3 + 2]dipolar cycloaddition of 1,6-allenynebenzaldehydes: construction of polycyclic ring systems

Article information

Article type
Communication
Submitted
24 Aug 2005
Accepted
15 Nov 2005
First published
24 Nov 2005

Green Chem., 2006,8, 25-28

Gold nanoparticle-catalysed [3 + 2]dipolar cycloaddition of 1,6-allenynebenzaldehydes: construction of polycyclic ring systems

A. K. Gupta, C. Y. Rhim, C. H. Oh, R. S. Mane and S. Han, Green Chem., 2006, 8, 25 DOI: 10.1039/B512034A

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