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Issue 23, 2006
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Self-assembly of luminescent ternary complexes between seven-coordinate lanthanide(III) complexes and chromophore bearing carboxylates and phosphonates

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Abstract

Luminescent lanthanide complexes have been prepared by exploiting the interaction between lanthanide DO3A complexes and chromophore bearing carboxylates or phosphonates. This interaction can be utilised to probe the choice of sensitising chromophore suited to a given lanthanide. Furthermore, ternary complexes obtained from chromophore appended carboxylates dissociate in the presence of phosphate, while those obtained from phosphonates do not.

Graphical abstract: Self-assembly of luminescent ternary complexes between seven-coordinate lanthanide(iii) complexes and chromophore bearing carboxylates and phosphonates

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Publication details

The article was received on 16 Jan 2006, accepted on 15 Feb 2006 and first published on 28 Apr 2006


Article type: Paper
DOI: 10.1039/B600598E
Citation: Dalton Trans., 2006,0, 2907-2912

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    Self-assembly of luminescent ternary complexes between seven-coordinate lanthanide(III) complexes and chromophore bearing carboxylates and phosphonates

    S. J. A. Pope, B. P. Burton-Pye, R. Berridge, T. Khan, P. J. Skabara and S. Faulkner, Dalton Trans., 2006, 0, 2907
    DOI: 10.1039/B600598E

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