Issue 43, 2006

Rational ligand design for metal ion recognition. Synthesis of a N-benzylated N2S3-donor macrocycle for enhanced silver(i) discrimination

Abstract

Four previously documented ligand design strategies for achieving Ag(I) discrimination have been applied to the design of a new N-benzylated N2S3-donor macrocycle; the latter shows high selectivity for Ag(I) over Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) in log K and bulk membrane transport studies.

Graphical abstract: Rational ligand design for metal ion recognition. Synthesis of a N-benzylated N2S3-donor macrocycle for enhanced silver(i) discrimination

Supplementary files

Article information

Article type
Communication
Submitted
19 Sep 2006
Accepted
20 Sep 2006
First published
29 Sep 2006

Dalton Trans., 2006, 5115-5117

Rational ligand design for metal ion recognition. Synthesis of a N-benzylated N2S3-donor macrocycle for enhanced silver(I) discrimination

I. M. Vasilescu, D. J. Bray, J. K. Clegg, L. F. Lindoy, G. V. Meehan and G. Wei, Dalton Trans., 2006, 5115 DOI: 10.1039/B613636M

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