Aurolysis of α-C-deprotonated group 6 aminocarbene and thiocarbene complexes with Ph3PAu+†
Abstract
Deprotonated Fischer-type aminocarbene complexes, (CO)5MC(NR2)CH3 (M = Cr or W; R = Me or
CH2)SPh}Cr(CO)5 in a mixed crystal with [Ph3PAuSPh]Cr(CO)5, precisely this coordination mode is present. The latter component of the mixed crystal has also been prepared independently of the