Magnetic anisotropy of two trinuclear and tetranuclear CrIIINiII cyanide-bridged complexes with spin ground states S = 4 and 5†‡
Abstract
The trinuclear and the tetranuclear complexes [{iPrtacnCr(CN)3}2{Ni(cyclam)}](NO3)2·5H2O 1 (
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* Corresponding authors
a
ICMMO-Equipe Chimie Inorganique, CNRS UMR 8182, Université Paris-Sud, Bât 420, Orsay, France
E-mail:
mallah@icmo.u-psud.fr
Fax: (+33) 1 69154754
Tel: (+33) 1 69 15 47 49
b IPCMS-GMI, UMR CNRS 7504, 23, rue du Loess, B.P. 43, Strasbourg Cedex 2, France
c CEA/Saclay, SCM, Bat. 125, Gif-sur-Yvette, France
d Laboratoire des Champs Magnétiques Intenses, UPR CNRS 5021, 25, avenue des Martyrs, B.P. 166, Grenoble Cedex 9, France
The trinuclear and the tetranuclear complexes [{iPrtacnCr(CN)3}2{Ni(cyclam)}](NO3)2·5H2O 1 (
J. Rebilly, L. Catala, G. Charron, G. Rogez, E. Rivière, R. Guillot, P. Thuéry, A. Barra and T. Mallah, Dalton Trans., 2006, 2818 DOI: 10.1039/B517417A
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