Issue 8, 2006
From the journal:

Dalton Transactions

Coordinative flexibility in hydrotris(methimazolyl)borate divalent metal compounds

Anıl Çetina  and  Christopher J. Ziegler*a  

* Corresponding authors

a Department of Chemistry, University of Akron, Akron, OH, USA
E-mail: ziegler@uakron.edu

Abstract

Three divalent closed d shell metal complexes of the hydrotris(methimazolyl)borate ligand, [Ca(mt)2]·6H2O, [Ba(mt)2](H2O)2, and Hg4(mt)4Cl4, were synthesized and characterized by single crystal X-ray diffraction; the three structures reveal very different ligand binding modes for each metal ion.

Graphical abstract: Coordinative flexibility in hydrotris(methimazolyl)borate divalent metal compounds

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Article information

DOI
https://doi.org/10.1039/B516558J
Article type
Communication
Submitted
22 Nov 2005
Accepted
02 Dec 2005
First published
14 Dec 2005

Dalton Trans., 2006, 1006-1008

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Coordinative flexibility in hydrotris(methimazolyl)borate divalent metal compounds

A. Çetin and C. J. Ziegler, Dalton Trans., 2006, 1006 DOI: 10.1039/B516558J

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