Issue 11, 2006

Thiacalix[3]pyridine produces a stable mononuclear rhodium(ii) complex with mutual Jahn–Teller effect

Abstract

Thiacalix[3]pyridine (Py3S3) consists of pyridines and bridging sulfur atoms producing a stable octahedral mononuclear Rh(II) complex [RhII(Py3S3)2]2+ showing mutual Jahn–Teller effect, a metal based reversible redox couple of Rh(III/II) at 0.02 V vs. SCE and a g > g|| relationship in EPR measurements.

Graphical abstract: Thiacalix[3]pyridine produces a stable mononuclear rhodium(ii) complex with mutual Jahn–Teller effect

Supplementary files

Article information

Article type
Communication
Submitted
09 Nov 2005
Accepted
06 Dec 2005
First published
19 Dec 2005

Dalton Trans., 2006, 1374-1376

Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn–Teller effect

R. T. Hamazawa, T. Nishioka, I. Kinoshita, T. Takui, R. Santo and A. Ichimura, Dalton Trans., 2006, 1374 DOI: 10.1039/B515926A

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