Issue 6, 2006

A 3D porous lanthanide–fumarate framework with water hexamer occupied cavities, exhibiting a reversible dehydration and rehydration procedure

Abstract

[Sm2(fumarate)3(H2O)4]·3H2O, a new porous pillared layer framework with 0D cavities for the accommodation of chair-like hexameric water clusters, possesses three kinds of fumarate ligand with their two COO ends adopting different coordination modes and shows reversible de- and re-hydration behavior.

Graphical abstract: A 3D porous lanthanide–fumarate framework with water hexamer occupied cavities, exhibiting a reversible dehydration and rehydration procedure

Supplementary files

Article information

Article type
Communication
Submitted
25 Oct 2005
Accepted
01 Dec 2005
First published
15 Dec 2005

Dalton Trans., 2006, 765-768

A 3D porous lanthanide–fumarate framework with water hexamer occupied cavities, exhibiting a reversible dehydration and rehydration procedure

W. Zhu, Z. Wang and S. Gao, Dalton Trans., 2006, 765 DOI: 10.1039/B515151A

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