Issue 13, 2006
From the journal:

Dalton Transactions

A structural and magnetic study of organolanthanide(iii) amides†

Richard A. Layfield,*a   Alan Bashall,b   Mary McPartlin,b   Jeremy M. Rawsona  and  Dominic S. Wrighta  

* Corresponding authors

a Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: ral34@cam.ac.uk
Fax: +44 1223 336339
Tel: +44 1223 336324

b Department of Health and Biological Science, London Metrolpolitan University, London, UK

Abstract

The syntheses, structures and magnetic properties of the series of dimeric organolanthanide(III) amides [Cp2Ln{2-NH-4,6-Me2pm}]2 [Ln = Nd (1), Gd (2), Dy (3), Yb (4) and pm = pyrimidine], which are formed from the deprotonation of 2-amino-4,6-dimethylpyrimidine by the corresponding lanthanide tris-cyclopentadienide, are reported. The synthesis and structure of [{Cp2Yb(2-NH-4-MeO-6-MeOpm)2(µ3-O)(YbCp)] (5), formed in a similar deprotonation reaction but in the presence of adventitious water, is also reported.

Graphical abstract: A structural and magnetic study of organolanthanide(iii) amides

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Article information

DOI
https://doi.org/10.1039/B514470A
Article type
Paper
Submitted
12 Oct 2005
Accepted
29 Nov 2005
First published
14 Dec 2005

Dalton Trans., 2006, 1660-1666

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A structural and magnetic study of organolanthanide(III) amides

R. A. Layfield, A. Bashall, M. McPartlin, J. M. Rawson and D. S. Wright, Dalton Trans., 2006, 1660 DOI: 10.1039/B514470A

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