Issue 13, 2006

A structural and magnetic study of organolanthanide(iii) amides

Abstract

The syntheses, structures and magnetic properties of the series of dimeric organolanthanide(III) amides [Cp2Ln{2-NH-4,6-Me2pm}]2 [Ln = Nd (1), Gd (2), Dy (3), Yb (4) and pm = pyrimidine], which are formed from the deprotonation of 2-amino-4,6-dimethylpyrimidine by the corresponding lanthanide tris-cyclopentadienide, are reported. The synthesis and structure of [{Cp2Yb(2-NH-4-MeO-6-MeOpm)23-O)(YbCp)] (5), formed in a similar deprotonation reaction but in the presence of adventitious water, is also reported.

Graphical abstract: A structural and magnetic study of organolanthanide(iii) amides

Supplementary files

Article information

Article type
Paper
Submitted
12 Oct 2005
Accepted
29 Nov 2005
First published
14 Dec 2005

Dalton Trans., 2006, 1660-1666

A structural and magnetic study of organolanthanide(III) amides

R. A. Layfield, A. Bashall, M. McPartlin, J. M. Rawson and D. S. Wright, Dalton Trans., 2006, 1660 DOI: 10.1039/B514470A

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