Dimetallo[3.3]para- and metacyclophanes by self-assembly of pyridylmethyl armed-monoazatrithia- and monoazadithiaoxa-12-crown-4 ethers with Ag+ ions

Yoichi Habata; Futoshi Osaka

doi:10.1039/B513931G

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Dimetallo[3.3]para- and metacyclophanes by self-assembly of pyridylmethyl armed-monoazatrithia- and monoazadithiaoxa-12-crown-4 ethers with Ag⁺ ions†

Yoichi Habata*^ab and Futoshi Osaka^a

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* Corresponding authors

^a Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba, Japan

^b Research Center for Materials with Integrated Properties, Toho University, 2-2-1 Miyama, Funabashi, Chiba, Japan

Abstract

New pyridylmethyl armed-monoazadithiaoxa- and monoazatrithia-12-crown-4 have been prepared. The structures of the Ag⁺ complexes of the new ligands were investigated by X-ray crystallography, ¹H NMR titrations, and FAB-MS measurements. In all cases, the Ag⁺ complexes form dimetallo[3.3]para- or metacyclophane structures depending on the position of the N atom of the pyridine rings.

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Article information

DOI: https://doi.org/10.1039/B513931G
Article type: Paper
Submitted: 30 Sep 2005
Accepted: 03 Jan 2006
First published: 20 Jan 2006

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Dalton Trans., 2006, 1836-1841

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Dimetallo[3.3]para- and metacyclophanes by self-assembly of pyridylmethyl armed-monoazatrithia- and monoazadithiaoxa-12-crown-4 ethers with Ag⁺ ions

Y. Habata and F. Osaka, Dalton Trans., 2006, 1836 DOI: 10.1039/B513931G

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Dalton Transactions