Issue 16, 2006
From the journal:

Dalton Transactions

Polynuclear vanadium complexes from thermal decomposition of [V3O(O2CPh)6(H2O)3]Cl

E. Carolina Sañudo,a   Andrew A. Smith,a   Pamela V. Mason,a   Madeleine Helliwell,a   Guillem Aromíb  and  Richard E. P. Winpenny*a  

* Corresponding authors

a Department of Chemistry, University of Manchester, Manchester, UK

b Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 637, Barcelona, Spain

Abstract

Solid-state decomposition of [V3O(O2CPh)6(H2O)3]Cl at 300 °C followed by alcoholysis of the product gives the new vanadium complexes [V6O6(PhCO2)6(CH3O)6(CH3OH)3] (1), [V6O6(PhCO2)6(C2H5O)6(C2H5OH)3] (2), [V6O6(PhCO2)6(C3H7O)6(C3H7OH)3] (3), [V6O6(PhCO2)6(C4H9O)6(C4H9OH)3] (4) and [V4O4(OCH3)6(O2CPh)2(HOCH3)2] (5). Complexes 2, 3 and 5 have been crystallographically characterised. DC magnetic susceptibility studies on complex 3 shows antiferromagnetic coupling leading to a S = 0 spin ground state.

Graphical abstract: Polynuclear vanadium complexes from thermal decomposition of [V3O(O2CPh)6(H2O)3]Cl

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B510105K
Article type
Paper
Submitted
18 Jul 2005
Accepted
05 Jan 2006
First published
19 Jan 2006

Dalton Trans., 2006, 1981-1987

Permissions

Request permissions

Polynuclear vanadium complexes from thermal decomposition of [V3O(O2CPh)6(H2O)3]Cl

E. C. Sañudo, A. A. Smith, P. V. Mason, M. Helliwell, G. Aromí and R. E. P. Winpenny, Dalton Trans., 2006, 1981 DOI: 10.1039/B510105K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements