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Issue 37, 2006
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First steps towards dissolution of NaSO4 by water

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Abstract

NaSO4(H2O)n (n = 0–4) clusters have been generated in the gas phase as model systems to simulate the first dissolution steps of sulfate salts in water; photoelectron spectroscopy and theoretical calculations indicate that the first three water molecules strongly interact with both Na+ and SO42−, forming a three-water solvation ring to start to pry apart the Na+SO42− contact ion pair.

Graphical abstract: First steps towards dissolution of NaSO4− by water

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Publication details

The article was received on 12 Jul 2006, accepted on 31 Jul 2006 and first published on 07 Aug 2006


Article type: Communication
DOI: 10.1039/B609941F
Citation: Phys. Chem. Chem. Phys., 2006,8, 4294-4296
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    First steps towards dissolution of NaSO4 by water

    X. Wang, H. Woo, B. Jagoda-Cwiklik, P. Jungwirth and L. Wang, Phys. Chem. Chem. Phys., 2006, 8, 4294
    DOI: 10.1039/B609941F

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