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Issue 20, 2006
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Proton tunneling estimates for malonaldehyde vibrations from supersonic jet and matrix quenching experiments

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Abstract

FTIR tunneling splittings for a range of fundamental excitations of malonaldehyde are determined from adiabatic cooling and symmetry breaking experiments in three different molecular states (isolated, coated by Ar layers and embedded in bulk Ar matrices), showing that there is room for improvement in available theoretical models.

Graphical abstract: Proton tunneling estimates for malonaldehyde vibrations from supersonic jet and matrix quenching experiments

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Publication details

The article was received on 15 Feb 2006, accepted on 27 Mar 2006 and first published on 20 Apr 2006


Article type: Communication
DOI: 10.1039/B602319N
Citation: Phys. Chem. Chem. Phys., 2006,8, 2344-2348

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    Proton tunneling estimates for malonaldehyde vibrations from supersonic jet and matrix quenching experiments

    T. N. Wassermann, D. Luckhaus, S. Coussan and M. A. Suhm, Phys. Chem. Chem. Phys., 2006, 8, 2344
    DOI: 10.1039/B602319N

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