A self-assembled acid-functionalised monolayer on a gold surface has an interfacial pH 2.93 more acidic than the bulk and surface pKa very similar to that of the free acid.
M. Rooth and A. M. Shaw, Phys. Chem. Chem. Phys., 2006, 8, 4741 DOI: 10.1039/B611346J
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