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Issue 40, 2006
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Quantitative chirality synchronization in trifluoroethanol dimers

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Abstract

2,2,2-Trifluoroethanol molecules synchronize their transiently chiral gauche configurations upon dimerization in supersonic jet expansions, while they avoid an energetically competitive heteroconfigurational hydrogen bonded dimer topology predicted by extensive quantum chemical calculations.

Graphical abstract: Quantitative chirality synchronization in trifluoroethanol dimers

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Publication details

The article was received on 12 Jul 2006, accepted on 05 Sep 2006 and first published on 21 Sep 2006


Article type: Communication
DOI: 10.1039/B609868A
Citation: Phys. Chem. Chem. Phys., 2006,8, 4664-4667

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    Quantitative chirality synchronization in trifluoroethanol dimers

    T. Scharge, T. Häber and M. A. Suhm, Phys. Chem. Chem. Phys., 2006, 8, 4664
    DOI: 10.1039/B609868A

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