Issue 29, 2006
From the journal:

Physical Chemistry Chemical Physics

Near ultraviolet photolysis of deuterated pyrrole†

Bríd Cronin,a   Adam L. Devine,a   Michael G. D. Nixa  and  Michael N. R. Ashfolda  

a School of Chemistry, University of Bristol, Bristol, U.K.
E-mail: Mike.Ashfold@bristol.ac.uk
Fax: (117)-9250612
Tel: (117)-9288312

Abstract

High resolution time-of-flight (TOF) measurements of the D atom fragments arising in the near ultraviolet (UV) photodissociation of deuterated pyrrole are reported. Structures evident in the measured TOF spectra are all interpretable in terms of N–D bond fission, and population of selected vibrational states of the pyrrolyl-d4 co-fragment—thereby clarifying previous uncertainties regarding the branching into different vibronic states of the pyrrolyl radical following UV excitation of pyrrole.

Graphical abstract: Near ultraviolet photolysis of deuterated pyrrole

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Article information

DOI
https://doi.org/10.1039/B607350F
Article type
Paper
Submitted
24 May 2006
Accepted
13 Jun 2006
First published
23 Jun 2006

Phys. Chem. Chem. Phys., 2006,8, 3440-3445

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Near ultraviolet photolysis of deuterated pyrrole

B. Cronin, A. L. Devine, M. G. D. Nix and M. N. R. Ashfold, Phys. Chem. Chem. Phys., 2006, 8, 3440 DOI: 10.1039/B607350F

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