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Issue 8, 2006
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Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(v) phosphate frameworks

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Abstract

The synthesis and structural characterization of three new polyoxomolybdenum(V) phosphate frameworks have been achieved by using dimeric {Mo6}2 moieties as inorganic building blocks and protonated organic amines as counter ions. The structure-directing role of the organic cations was investigated and it was shown, that the geometry and the rigidity of the amines as well as their hydrogen bonding capabilities influence the formation of layered or chain-like superstructures.

Graphical abstract: Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(v) phosphate frameworks

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Article information


Submitted
12 Apr 2006
Accepted
30 Jun 2006
First published
12 Jul 2006

CrystEngComm, 2006,8, 629-634
Article type
Paper

Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks

C. Streb, D. Long and L. Cronin, CrystEngComm, 2006, 8, 629
DOI: 10.1039/B605285A

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