Issue 8, 2006
From the journal:

CrystEngComm

Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(v) phosphate frameworks

Carsten Streb,a   De-Liang Longa  and  Leroy Cronin*a  

* Corresponding authors

a WestCHEM, Department of Chemistry, Joseph Black Building, University of Glasgow, University Avenue, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk
Fax: +44-141-330-4888
Tel: +44-141-330-6650

Abstract

The synthesis and structural characterization of three new polyoxomolybdenum(V) phosphate frameworks have been achieved by using dimeric {Mo6}2 moieties as inorganic building blocks and protonated organic amines as counter ions. The structure-directing role of the organic cations was investigated and it was shown, that the geometry and the rigidity of the amines as well as their hydrogen bonding capabilities influence the formation of layered or chain-like superstructures.

Graphical abstract: Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(v) phosphate frameworks

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Article information

DOI
https://doi.org/10.1039/B605285A
Article type
Paper
Submitted
12 Apr 2006
Accepted
30 Jun 2006
First published
12 Jul 2006

CrystEngComm, 2006,8, 629-634

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Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks

C. Streb, D. Long and L. Cronin, CrystEngComm, 2006, 8, 629 DOI: 10.1039/B605285A

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