Issue 5, 2006
From the journal:

CrystEngComm

New observations of structural diversity in copper(ii) complexes of diphenylsulfimide

Kathryn E. Holmes,a   Paul F. Kelly,*a   Sophie H. Daleb  and  Mark R. J. Elsegooda  

* Corresponding authors

a Department of Chemistry, Loughborough University, Loughborough, Leics, UK
E-mail: P.F.Kelly@lboro.ac.uk
Fax: 01509 223925
Tel: 01509 222578

b Molecular Profiles Ltd, 8 Orchard Place, Nottingham Business Park, Nottingham, UK

Abstract

Reaction of S,S′-diphenylsulfimide, Ph2SNH (1), with Cu[BF4]2 in acetonitrile generates a solution from which six products may be crystallised: two polymorphs of [Cu(Ph2SNH)4][BF4]2, the inter-allogon [Cu(Ph2SNH)4]2[BF4]4, the mixed coordination system [Cu(Ph2SNH)4][Cu(Ph2SNH)5][BF4]4, five-coordinate [Cu(Ph2SNH)5][BF4]4 (2) and the nitrile adduct [Cu(Ph2SNH)3(Ph2SNC(Me)NH)][BF4]2 (3). Great structural diversity is also observed in the perchlorate [Cu(Ph2SNH)4][ClO4]2 (4) and [Cu(Ph2SNH)4]2[ClO4]4 (5) and nitrate [Cu(Ph2SNH)4][NO3]2 (6) and [Cu(Ph2SNH)4][Cu(Ph2SNH)5][NO3]4 (7) salts.

Graphical abstract: New observations of structural diversity in copper(ii) complexes of diphenylsulfimide

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Article information

DOI
https://doi.org/10.1039/B601230B
Article type
Paper
Submitted
26 Jan 2006
Accepted
27 Mar 2006
First published
10 Apr 2006

CrystEngComm, 2006,8, 391-402

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New observations of structural diversity in copper(II) complexes of diphenylsulfimide

K. E. Holmes, P. F. Kelly, S. H. Dale and M. R. J. Elsegood, CrystEngComm, 2006, 8, 391 DOI: 10.1039/B601230B

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