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Issue 39, 2006
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Silver-catalyzed hydrosilylation of aldehydes

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Silver triflate, either alone or in the presence of an appropriate phosphine or NHC ligand, has been shown to catalyze the chemoselective hydrosilylation of aromatic and aliphatic aldehydes to yield silyl ethers, thus representing the first systematic application of silver species as catalysts for the hydrosilylation of unsaturated organic substrates.

Graphical abstract: Silver-catalyzed hydrosilylation of aldehydes

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The article was received on 07 Jul 2006, accepted on 03 Aug 2006 and first published on 23 Aug 2006

Article type: Communication
DOI: 10.1039/B609679D
Citation: Chem. Commun., 2006,0, 4104-4106
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    Silver-catalyzed hydrosilylation of aldehydes

    B. M. Wile and M. Stradiotto, Chem. Commun., 2006, 0, 4104
    DOI: 10.1039/B609679D

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