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Issue 39, 2006
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Enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

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Abstract

The catalytic asymmetric 1,2-addition of a series of arylboronic acids to 2,2,2-trifluoroacetophenones is described with high isolated yields (up to 96%) and good enantioselectivities (up to 83% ee) using a rhodium(I)/phosphoramidite catalyst.

Graphical abstract: Enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

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Publication details

The article was received on 04 Jul 2006, accepted on 08 Aug 2006 and first published on 22 Aug 2006


Article type: Communication
DOI: 10.1039/B609453H
Chem. Commun., 2006, 4093-4095

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    Enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

    S. L. X. Martina, R. B. C. Jagt, J. G. de Vries, B. L. Feringa and A. J. Minnaard, Chem. Commun., 2006, 4093
    DOI: 10.1039/B609453H

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