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Issue 39, 2006
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Enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

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Abstract

The catalytic asymmetric 1,2-addition of a series of arylboronic acids to 2,2,2-trifluoroacetophenones is described with high isolated yields (up to 96%) and good enantioselectivities (up to 83% ee) using a rhodium(I)/phosphoramidite catalyst.

Graphical abstract: Enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

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Article information


Submitted
04 Jul 2006
Accepted
08 Aug 2006
First published
22 Aug 2006

Chem. Commun., 2006, 4093-4095
Article type
Communication

Enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

S. L. X. Martina, R. B. C. Jagt, J. G. de Vries, B. L. Feringa and A. J. Minnaard, Chem. Commun., 2006, 4093
DOI: 10.1039/B609453H

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