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Issue 35, 2006
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Encapsulation of a guest molecule in a strained form: an extended 36-membered dodecanuclear manganese metallamacrocycle that accommodates a cyclooctane in the S4 symmetry conformation

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Abstract

An extended 36-membered dodecanuclear manganese metallamacrocycle with S12 symmetry has been synthesized using the ligand N-cyclohexanoylsalicylhydrazide (H3chxshz) by a self-assembly that accommodates a cyclooctane of conformationally strained S4 symmetry in its hydrophobic cavity.

Graphical abstract: Encapsulation of a guest molecule in a strained form: an extended 36-membered dodecanuclear manganese metallamacrocycle that accommodates a cyclooctane in the S4 symmetry conformation

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Publication details

The article was received on 31 May 2006, accepted on 11 Jul 2006 and first published on 31 Jul 2006


Article type: Communication
DOI: 10.1039/B607675K
Citation: Chem. Commun., 2006,0, 3699-3701
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    Encapsulation of a guest molecule in a strained form: an extended 36-membered dodecanuclear manganese metallamacrocycle that accommodates a cyclooctane in the S4 symmetry conformation

    R. P. John, J. Park, D. Moon, K. Lee and M. S. Lah, Chem. Commun., 2006, 0, 3699
    DOI: 10.1039/B607675K

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