Issue 32, 2006
From the journal:

Chemical Communications

A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes†

Maximilian Dochnahl,a   Jens-Wolfgang Pissarek,a   Siegfried Blechert,*a   Karolin Löhnwitzb  and  Peter W. Roesky*b  

* Corresponding authors

a Technische Universität Berlin, Institut für Chemie, Straße des 17. Juni 135, 10623 Berlin, Germany
E-mail: blechert@chem.tu-berlin.de
Fax: +49 (0)30-31 42 36 19
Tel: +49 (0)30-31 42 23 55

b Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstraße 34-36, 14195 Berlin, Germany
E-mail: roesky@chemie.fu-berlin.de
Fax: +49 (0)30-83 85 24 40
Tel: +49 (0)30-83 85 40 04

Abstract

The new zinc compound N-cyclohexyl-2-(cyclohexylamino)troponiminate zinc methyl, [(Cy)2ATI]ZnMe (2), was synthesized and showed a superior reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to previously reported homogeneous zinc complexes.

Graphical abstract: A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes

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Article information

DOI
https://doi.org/10.1039/B607597E
Article type
Communication
Submitted
30 May 2006
Accepted
11 Jul 2006
First published
24 Jul 2006

Chem. Commun., 2006, 3405-3407

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A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes

M. Dochnahl, J. Pissarek, S. Blechert, K. Löhnwitz and P. W. Roesky, Chem. Commun., 2006, 3405 DOI: 10.1039/B607597E

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