Issue 30, 2006
From the journal:

Chemical Communications

An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine†

Daljit S. Matharu,a   David J. Morris,a   Guy J. Clarksonb  and  Martin Wills*a  

* Corresponding authors

a Asymmetric Catalysis Group, Coventry, UK
E-mail: m.wills@warwick.ac.uk
Fax: +44 24 7652 4112
Tel: +44 24 7652 3260

b X-ray Crystallography Unit, Department of Chemistry, The University of Warwick, Coventry, UK

Abstract

A Rh/tetramethylcyclopentadienyl complex containing a tethered functionality has been demonstrated to give excellent results in the asymmetric transfer hydrogenation of ketones in both aqueous and formic acid/triethylamine media.

Graphical abstract: An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine

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Article information

DOI
https://doi.org/10.1039/B606288A
Article type
Communication
Submitted
03 May 2006
Accepted
05 Jun 2006
First published
23 Jun 2006

Chem. Commun., 2006, 3232-3234

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An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine

D. S. Matharu, D. J. Morris, G. J. Clarkson and M. Wills, Chem. Commun., 2006, 3232 DOI: 10.1039/B606288A

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