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Issue 16, 2006
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An iron(III) phosphonate cluster containing a nonanuclear ring

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Abstract

This communication reports the first example of cyclic ferric clusters with an odd number of iron atoms capped by phosphonate ligands, namely, [Fe9(μ-OH)7(μ-O)2(O3PC6H9)8(py)12]. The magnetic studies support a S = 1/2 ground state with an exchange coupling constant of about J ≈ −30 K.

Graphical abstract: An iron(iii) phosphonate cluster containing a nonanuclear ring

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Publication details

The article was received on 18 Jan 2006, accepted on 27 Feb 2006 and first published on 13 Mar 2006


Article type: Communication
DOI: 10.1039/B600763E
Citation: Chem. Commun., 2006,0, 1745-1747
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    An iron(III) phosphonate cluster containing a nonanuclear ring

    H. Yao, J. Wang, Y. Ma, O. Waldmann, W. Du, Y. Song, Y. Li, L. Zheng, S. Decurtins and X. Xin, Chem. Commun., 2006, 0, 1745
    DOI: 10.1039/B600763E

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