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Issue 17, 2006
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Synthesis and structural characterization of the first metal organic thallium antimonide

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Abstract

The first metal organic thallium antimonide, the heterocycle [Me2TlSb(SiMe3)2]3, was synthesized by reaction of [Me2AlSb(SiMe3)2]3 with the Lewis acid–base adduct dmap-TlMe3 (dmap = 4-dimethylaminopyridine). The analogous TlBi heterocycle [Me2TlBi(SiMe3)2]3 couldn't be isolated due to its limited thermal stability in solution.

Graphical abstract: Synthesis and structural characterization of the first metal organic thallium antimonide

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Article information


Submitted
20 Dec 2005
Accepted
10 Mar 2006
First published
20 Mar 2006

Chem. Commun., 2006, 1860-1861
Article type
Communication

Synthesis and structural characterization of the first metal organic thallium antimonide

S. Schulz, F. Thomas and M. Nieger, Chem. Commun., 2006, 1860
DOI: 10.1039/B518072D

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