Issue 17, 2006

Synthesis and structural characterization of the first metal organic thallium antimonide

Abstract

The first metal organic thallium antimonide, the heterocycle [Me2TlSb(SiMe3)2]3, was synthesized by reaction of [Me2AlSb(SiMe3)2]3 with the Lewis acid–base adduct dmap-TlMe3 (dmap = 4-dimethylaminopyridine). The analogous TlBi heterocycle [Me2TlBi(SiMe3)2]3 couldn't be isolated due to its limited thermal stability in solution.

Graphical abstract: Synthesis and structural characterization of the first metal organic thallium antimonide

Supplementary files

Article information

Article type
Communication
Submitted
20 Dec 2005
Accepted
10 Mar 2006
First published
20 Mar 2006

Chem. Commun., 2006, 1860-1861

Synthesis and structural characterization of the first metal organic thallium antimonide

S. Schulz, F. Thomas and M. Nieger, Chem. Commun., 2006, 1860 DOI: 10.1039/B518072D

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