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Issue 12, 2006
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Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts

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Abstract

Remarkable selectivity is achieved in the cleavage of benzyl ethers using ball-shaped palladium nanocatalysts, Pd@MCM-48, in an MCM-48 matrix. The unique nanocatalysts not only feature unprecedented complete hydrogenolysis selectivity of a benzyl ether over hydrogenation of a double bond, but also demonstrate selective cleavage of unsubstituted benzyl ether over substituted benzyl ethers.

Graphical abstract: Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts

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Article information


Submitted
02 Dec 2005
Accepted
30 Jan 2006
First published
16 Feb 2006

Chem. Commun., 2006, 1325-1327
Article type
Communication

Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts

H. Lee, S. Ryu, H. Kang, Y. Jun and J. Cheon, Chem. Commun., 2006, 1325
DOI: 10.1039/B517082F

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