Issue 47, 2006
From the journal:

Chemical Communications

A simple asymmetric organocatalytic approach to optically active cyclohexenones†

Armando Carlone,a   Mauro Marigo,a   Chris North,a   Aitor Landaa  and  Karl Anker Jørgensen*a  

* Corresponding authors

a Danish National Research Foundation: Center for Catalysis, Department of Chemistry, Aarhus University, Aarhus C, Denmark
E-mail: kaj@chem.au.dk
Fax: +(45) 8619 6199
Tel: +(45) 8942 3910

Abstract

Optically active 2,5-disubstituted-cyclohexen-2-one derivatives have been prepared in a one-pot process consisting of five reaction steps: an organocatalytic asymmetric conjugated addition of β-ketoesters to α,β-unsaturated aldehydes that proceeds in aqueous solutions or under solvent-free conditions has been implemented in a multi-step process.

Graphical abstract: A simple asymmetric organocatalytic approach to optically active cyclohexenones

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Article information

DOI
https://doi.org/10.1039/B611366D
Article type
Communication
Submitted
08 Aug 2006
Accepted
18 Sep 2006
First published
05 Oct 2006

Chem. Commun., 2006, 4928-4930

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A simple asymmetric organocatalytic approach to optically active cyclohexenones

A. Carlone, M. Marigo, C. North, A. Landa and K. A. Jørgensen, Chem. Commun., 2006, 4928 DOI: 10.1039/B611366D

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