Issue 40, 2006
From the journal:

Chemical Communications

Highly-oxidised, sulfur-rich, mixed-valence vanadium(iv/v) complexes

Michelle K. Taylor,a   David J. Evansa  and  Charles G. Young*a  

* Corresponding authors

a School of Chemistry, University of Melbourne, Victoria 3010, Australia
E-mail: cgyoung@unimelb.edu.au
Fax: +61393475180

Abstract

The reactions of [V2(μ-S2)2(S2CNR2)4] (R = alkyl) with NOBF4 produce highly-oxidised, sulfur-rich, V(IV/V) complexes, [V2(μ-S2)2(S2CNR2)4]BF4, that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.

Graphical abstract: Highly-oxidised, sulfur-rich, mixed-valence vanadium(iv/v) complexes

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Article information

DOI
https://doi.org/10.1039/B610036H
Article type
Communication
Submitted
13 Jul 2006
Accepted
15 Aug 2006
First published
05 Sep 2006

Chem. Commun., 2006, 4245-4246

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Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes

M. K. Taylor, D. J. Evans and C. G. Young, Chem. Commun., 2006, 4245 DOI: 10.1039/B610036H

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