Chiral palladium bis(phosphite)				PCP-pincer complexes via ligand C–H activation

R. Angharad Baber; Robin B. Bedford; Michael Betham; Michael E. Blake; Simon J. Coles; Mairi F. Haddow; Michael B. Hursthouse; A. Guy Orpen; Lukasz T. Pilarski; Paul G. Pringle; Richard L. Wingad

doi:10.1039/B609704A

Chiral palladium bis(phosphite)PCP-pincer complexes vialigand C–H activation†

R. Angharad Baber,^a Robin B. Bedford,*^a Michael Betham,^a Michael E. Blake,^b Simon J. Coles,^c Mairi F. Haddow,^a Michael B. Hursthouse,^c A. Guy Orpen,^a Lukasz T. Pilarski,^a Paul G. Pringle*^a and Richard L. Wingad^a

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^a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: r.bedford@bristol.ac.uk

^b Department of Chemistry, University of Exeter, Exeter, UK

^c EPSRC National Crystallography Service, Department of Chemistry, University of Southampton, Highfield Road, Southampton, UK

Abstract

The synthesis of a range of chiral palladium bis(phosphite) pincer complexes has been achieved via C–H activation of the parent ligands and one of the complexes formed shows good activity in the catalytic allylation of aldehydes.

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Chiral palladium bis(phosphite)PCP-pincer complexes vialigand C–H activation†

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Chiral palladium bis(phosphite) PCP-pincer complexes via ligand C–H activation

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