Issue 42, 2006
From the journal:

Chemical Communications

Mononuclear copper(ii)–hydroperoxo complex derived from reaction of copper(i) complex with dioxygen as a model of DβM and PHM†‡

Tatsuya Fujii,a   Syuhei Yamaguchi,a   Yasuhiro Funahashi,a   Tomohiro Ozawa,a   Takehiko Tosha,b   Teizo Kitagawab  and  Hideki Masuda*a  

* Corresponding authors

a Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya, Japan
E-mail: masuda.hideki@nitech.ac.jp
Fax: +81 52 735 5209
Tel: +81 52 735 5228

b Center of Integrative Bioscience, Okazaki National Research Institutes, Myodaiji, Okazaki, Japan

Abstract

A mononuclear copper(II)–hydroperoxo species has been generated by the reaction of Cu(I)–H2BPPA complex with dioxygen, which illustrates the enzymatic reaction process of the CuB site in the DβM and PHM.

Graphical abstract: Mononuclear copper(ii)–hydroperoxo complex derived from reaction of copper(i) complex with dioxygen as a model of DβM and PHM

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Article information

DOI
https://doi.org/10.1039/B609673E
Article type
Communication
Submitted
07 Jul 2006
Accepted
23 Aug 2006
First published
13 Sep 2006

Chem. Commun., 2006, 4428-4430

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Mononuclear copper(II)–hydroperoxo complex derived from reaction of copper(I) complex with dioxygen as a model of DβM and PHM

T. Fujii, S. Yamaguchi, Y. Funahashi, T. Ozawa, T. Tosha, T. Kitagawa and H. Masuda, Chem. Commun., 2006, 4428 DOI: 10.1039/B609673E

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